A Comparative Study of Ozonation,Homogeneous Catalytic Ozonation,and Photocatalytic Ozonation for C.I. Reactive Red 194 Azo Dye Degradation     

A. Özlem Yıldırım  Şermin Gül  Orkide Eren  Erdal Kuşvuran 《洁净——土壤、空气、水》2011,39(8):795-805

In this study, the decolorization, dearomatization, and mineralization efficiencies of different advanced oxidation processes (AOPs; namely O₃, O₃/Fe(II), O₃/Fe(II)/UVA, and O₃/TiO₂/UVA) were investigated for the azo dye C.I. Reactive Red 194 (RR194). The effects of pH (3–11), amount of TiO₂ (0.05–1 g/L), and concentration of Fe(II) (0.1–1.6 mM) were investigated for the applied methods. The decolorization and mineralization efficiencies of the photocatalytic ozonation system (O₃/TiO₂/UVA) were increased by decreasing the pH of the dye solution in contrast to the ozonation system (O₃). Decolorization of RR194 was increased in the photocatalytic ozonation system with an increasing amount of catalyst however, a decreasing was occurred for the homogeneous catalytic system (O₃/Fe(II)) when increasing the concentration of catalyst. The decolorization efficiency of the homogeneous catalytic system (O₃/Fe(II)) was enhanced when combined with UVA light. In our study, the most efficient method for dearomatization and mineralization was the O₃/TiO₂/UVA among the applied AOPs.  相似文献   

FRP管约束活性粉末混凝土方柱抗震性能研究     

邓宗才  顾佳培 《震灾防御技术》2019,14(4):769-780

为了探究纤维增强聚合物（fiber reinforced polymers，FRP）管约束活性粉末混凝土（reactive powder concrete，RPC）方柱在低周反复荷载作用下的抗震性能，利用有限元软件ABAQUS对FRP管约束RPC方柱进行了数值模拟，并对不同轴压比、配箍率和FRP管厚度条件下约束柱的抗震性能进行了分析。结果表明:采用有限元模型对FRP管约束RPC方柱进行模拟是可靠的，有限元模拟结果和试验结果吻合较好；轴压比为0.2~0.6时，峰值荷载随轴压比的增大而增大，轴压比为0.7时的峰值荷载较0.6时反而下降；配箍率、FRP管厚度的增加可以改善约束柱的抗震性能，延缓强度和刚度的退化；FRP管厚度为0.501mm时的约束效果最好。  相似文献   

A method for incorporating equilibrium chemical reactions into multiphase flow models for CO2 storage     

《Advances in water resources》2013

CO₂ injection and storage in deep saline aquifers involves many coupled processes, including multiphase flow, heat and mass transport, rock deformation and mineral precipitation and dissolution. Coupling is especially critical in carbonate aquifers, where minerals will tend to dissolve in response to the dissolution of CO₂ into the brine. The resulting neutralization will drive further dissolution of both CO₂ and calcite. This suggests that large cavities may be formed and that proper simulation may require full coupling of reactive transport and multiphase flow. We show that solving the latter may suffice whenever two requirements are met: (1) all reactions can be assumed to occur in equilibrium and (2) the chemical system can be calculated as a function of the state variables of the multiphase flow model (i.e., liquid and gas pressure, and temperature). We redefine the components of multiphase flow codes (traditionally, water and CO₂), so that they are conservative for all reactions of the chemical system. This requires modifying the traditional constitutive relationships of the multiphase flow codes, but yields the concentrations of all species and all reaction rates by simply performing speciation and mass balance calculations at the end of each time step. We applied this method to the H₂O–CO₂–Na–Cl–CaCO₃ system, so as to model CO₂ injection into a carbonate aquifer containing brine. Results were very similar to those obtained with traditional formulations, which implies that full coupling of reactive transport and multi-phase flow is not really needed for this kind of systems, but the resulting simplifications may make it advisable even for cases where the above requirements are not met. Regarding the behavior of carbonate rocks, we find that porosity development near the injection well is small because of the low solubility of calcite. Moreover, dissolution concentrates at the front of the advancing CO₂ plume because the brine below the plume tends to reach high CO₂ concentrations quite rapidly. We conclude that carbonate dissolution needs not to be feared.  相似文献   

Multidimensional analytical models for isotope ratios in groundwater pollutant plumes of organic contaminants undergoing different biodegradation kinetics     

Patrick Höhener  Olivier Atteia 《Advances in water resources》2010

This work presents analytical models which are able to predict contours of concentrations and isotope ratios of organic pollutants in homogeneous aquifers. Four analytical solutions of the advective–dispersive transport equation for reactive transport from the literature differing in assumptions regarding biodegradation kinetics were used. Stable isotope ratios are computed after modelling the individual reactive transport of isotopic species in the aquifer, which respond differently to fractionation by biodegradation or sorption. The main finding of this study is that the isotope ratios in the plumes are very sensitive to the assumptions underlying the biodegradation kinetics in the models. When biodegradation occurs throughout the core of the plume as first-order reaction, the transversal gradients in isotope ratios are smooth. When biodegradation occurs in a bi-molecular reaction with an electron acceptor (modelled by double-Monod kinetics), steep transversal isotope gradients are predicted. When the reaction rates approach instantaneous reaction along the plume fringes, isotope shifts in the core of the plume disappear. A model incorporating plume and fringe degradation produces the most plausible predictions of isotope ratios in this study. It is shown furthermore that isotope fractionation by sorption causes an even different pattern of isotope ratios, with positive shifts restricted to near the forerunning front of an expanding plume. The models developed in this work can serve for the validation of numerical models and may be incorporated in natural attenuation support systems such as e.g. BIOSCREEN.  相似文献   

Deposition rates, mixing intensity and organic content in two contrasting submarine canyons     

R. García  D. van Oevelen  L. Thomsen  E. Epping 《Progress in Oceanography》2008,76(2):192-215

The hydrographically different conditions characterising the Western Iberian Margin (NE Atlantic) and the Gulf of Lions (Mediterranean) may play an important role in determining the biogeochemical characteristics of the sediments. To investigate this, we compared the Nazaré and Cap de Creus canyons, and their respective adjacent open slopes in terms of the organic carbon (C_org) contents, chlorophyll-a (chl-a) concentrations, C:N and chl-a:phaeopigment ratios, and also in terms of modelled mixing intensities, chl-a and ²¹⁰Pb deposition and background concentrations in sediments. Chlorophyll-a and ²¹⁰Pb profiles were fitted simultaneously with a reactive transport model to estimate mixing intensity, deposition and background concentrations. Further, to account for the possibility that the decay of chl-a may be lower in the deep sea than in shallow areas, we estimated the model parameters with two models. In one approach (model 1), the temperature dependent decay rate of chl-a as given by Sun et al. [Sun, M.Y., Lee, C., Aller, R.C. (1993) Laboratory Studies of Oxic and Anoxic Degradation of chlorophyll-a in Long-Island sound sediments. Geochimica et Cosmochimica Acta, 57, 147-157] for estuaries was used. In the other approach (model 2), an extra parameter was estimated to derive the chlorophyll-a degradation rate. An F-test, taking into account the different number of parameters in the models, was used to single out the model that significantly fitted the data best. In most cases, the model parameters were best-explained with model 1, indicating the empirical relationship by Sun et al. (1993) is a valid means to estimate the chlorophyll-a degradation rate in deep sea sediments. To assess the robustness with which the model parameters were estimated we provide a first application of Bayesian analysis in the modelling of tracers in sediments. Bayesian analysis allows calculating the mean and standard deviation for each model parameter and correlations among parameters. The model parameters for stations for which ²¹⁰Pb and chlorophyll-a profiles were available were robustly fitted as evidenced by an average coefficient of variation of 0.22. C_org contents, chl-a concentrations, chl-a:phaeo ratios, mixing intensities, depositions and background concentrations of chl-a and ²¹⁰Pb indicated that the Cap de Creus canyon and adjacent slope were less active in terms of organic matter accumulation and burial than the Nazaré canyon and respective open slope.  相似文献   

Reactive flow models of the Anarraaq Zn–Pb–Ag deposit,Red Dog district,Alaska     

Christian Schardt  Grant Garven  Karen D. Kelley  David L. Leach 《Mineralium Deposita》2008,43(7):735-757

The Red Dog ore deposit district in the Brooks Range of northern Alaska is host to several high-grade, shale-hosted Zn + Pb deposits. Due to the complex history and deformation of these ore deposits, the geological and hydrological conditions at the time of formation are poorly understood. Using geological observations and fluid inclusion data as constraints, numerical heat and fluid flow simulations of the Anarraaq ore deposit environment and coupled reactive flow simulations of a section of the ore body were conducted to gain more insight into the conditions of ore body formation. Results suggest that the ore body and associated base metal zonation may have formed by the mixing of oxidized, saline, metal-bearing hydrothermal fluids (<200°C) with reducing, HS-rich pore fluids within radiolarite-rich host rocks. Sphalerite and galena concentrations and base metal sulfide distribution are primarily controlled by the nature of the pore fluids, i.e., the extent and duration of the HS⁻ source. Forward modeling results also predict the distribution of pyrite and quartz in agreement with field observations and indicate a reaction front moving from the initial mixing interface into the radiolarite rocks. Heuristic mass calculations suggest that ore grades and base metal accumulation comparable to those found in the field (18% Zn, 5% Pb) are predicted to be reached after about 0.3 My for initial conditions (30 ppm Zn, 3 ppm Pb; 20% deposition efficiency).  相似文献   

Simulation of a reactive tracer experiment using stochastic hydraulic conductivity fields     

Stefan Gödeke  Helmut Geistlinger  Anko Fischer  Hans-Hermann Richnow  Mario Schirmer 《Environmental Geology》2008,55(6):1255-1261

Reactive tracer tests are performed to derive flow, transport and in situ biodegradation parameters. This paper describes the 3D simulation of a reactive tracer test using the transition probability geostatistical approach. Fifty different equally probable aquifer realizations were generated based on the geological information of 107 boreholes in an area of 62,500 m². One realization was chosen for the reactive transport simulation based on the results of groundwater flow modeling and on particle tracking calculations for the site. Field velocities at the site vary between 0.4 and 3 m/d. The transport of the reactive tracers deuterium ring labeled toluene-d₅ and fully deuterated toluene-d₈ was simulated and first-order biodegradation rates of 0.017 d⁻¹ for toluene-d₅ and 0.012 d⁻¹ for toluene-d₈ were determined.  相似文献   

溴素的有机化学Ⅵ.多溴代邻羟基苯甲酸—2,3,5,6—四溴—1,4—苯二酯的合成     

崔伟  钱佐国  孙明昆  孙汉章 《中国海洋大学学报(自然科学版)》1997,(1)

由邻羟基苯甲酸、１，４—苯二酚和溴素起始，经溴代、氧化—溴代、形成酰氯和酰化等步骤，合成了三种新的多溴代邻羟基苯甲酸—２，３，５，６—四溴—１，４—苯二酯。通过对产物溴含量、ＩＲ和１ＨＮＭＲ的分析，验证了产物的结构  相似文献   

Optimisation of wave energy extraction with the Archimedes Wave Swing   总被引：2，自引：0，他引：2  

Duarte Valrio  Pedro Beiro  Jos S da Costa 《Ocean Engineering》2007,34(17-18):2330-2344

This paper addresses the Archimedes Wave Swing (an offshore wave energy converter, which produces electricity from sea waves). It compares the performances of latching control (a discrete, highly non-linear, intrinsically sub-optimum control strategy), of reactive control, of phase and amplitude control (two optimum control strategies that involve non-causal transfer functions, which have to be implemented with approximations, thus rending the control sub-optimum), and of feedback linearisation control (a non-linear control strategy). From extensive simulations it is concluded that the latter performs clearly better irrespective of the sea state, and leads to a significant increase of absorbed wave power.  相似文献   

Coupled Reactive Transport Modeling of Redox Processes in a Nitrate-Polluted Sandy Aquifer     

Konrad Miotliński 《Aquatic Geochemistry》2008,14(2):117-131

The reactive transport modeling of a complicated suite of reactions apparent in the aquifer during the application of N-containing fertilizers is reported. The unconfined sandy aquifer can be subdivided into an oxic zone which contains groundwater with oxygen and nitrate and an anoxic zone characterized by elevated iron and sulfate concentrations in groundwater. Oxygen and nitrate are being reduced by pyrite and organic matter that commonly apparent in the aquifer. The oxidation of pyrite is modeled using the local equilibrium approach, whereas decomposition of organic matter, with the adoption of kinetic approach. The system is buffered by dissolution of aluminum and iron oxides. The modeling process is a two-step procedure. First, the processes are modeled in the one-dimensional (1D) column using PHREEQC code. Subsequently, the calibrated and verified data were copied and used in two-dimensional (2D) PHAST model. Prior to the performance of reactive transport modeling operations with PHAST, a reliable flow model was executed. Finally, predictions are made for the distribution of water chemistry for the year 2008. Model predicts that sulfate derived from the ongoing pyrite oxidation is reduced by the dissolved organic carbon at the higher depth and forms pyrite by the reaction with iron. The results of this study highlight the importance of understanding the interplay between the transport and chemical reactions that occur during the input of nitrate to the aquifer. Reactive transport modeling incorporating the use of a newly developed code PHAST have proved to be a powerful tool for analyzing and quantifying such interactions.  相似文献